Write the preparation of,or discuss the properties of:
$(i)$ Xenon-Fluorine compounds
$(ii)$ Xenon-Oxygen compounds

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(A) $(i)$ Xenon-Fluorine compounds: Xenon forms three binary fluorides,$XeF_{2}$,$XeF_{4}$,and $XeF_{6}$,by the direct reaction of elements under appropriate experimental conditions.
$Xe_{(g)} + F_{2_{(g)}} \xrightarrow{673 \ K, \ 1 \ bar} XeF_{2_{(s)}}$ (excess)
$Xe_{(g)} + 2F_{2_{(g)}} \xrightarrow{873 \ K, \ 7 \ bar} XeF_{4_{(s)}}$ ($1:5$ ratio)
$Xe_{(g)} + 3F_{2_{(g)}} \xrightarrow{573 \ K, \ 60-70 \ bar} XeF_{6_{(s)}}$ ($1:20$ ratio)
$XeF_{6}$ can also be prepared by the interaction of $XeF_{4}$ and $O_{2}F_{2}$ at $143 \ K$: $XeF_{4} + O_{2}F_{2} \rightarrow XeF_{6} + O_{2}$.
Physical properties: $XeF_{2}$,$XeF_{4}$,and $XeF_{6}$ are colourless crystalline solids and sublime readily at $298 \ K$. Their structures are linear,square planar,and distorted octahedral,respectively.
Chemical properties: Xenon fluorides hydrolyse readily. $2XeF_{2_{(s)}} + 2H_{2}O_{(l)} \rightarrow 2Xe_{(g)} + 4HF_{(aq)} + O_{2_{(g)}}$. They react with fluoride ion acceptors to form cationic species and with fluoride ion donors to form fluoroanions: $XeF_{2} + PF_{5} \rightarrow [XeF]^{+} [PF_{6}]^{-}$.
$(ii)$ Xenon-Oxygen compounds: Hydrolysis of $XeF_{4}$ and $XeF_{6}$ with water gives $XeO_{3}$.
$6XeF_{4} + 12H_{2}O \rightarrow 4Xe + 2XeO_{3} + 24HF + 3O_{2}$
$XeF_{6} + 3H_{2}O \rightarrow XeO_{3} + 6HF$
Partial hydrolysis of $XeF_{6}$ gives oxyfluorides: $XeF_{6} + H_{2}O \rightarrow XeOF_{4} + 2HF$ and $XeF_{6} + 2H_{2}O \rightarrow XeO_{2}F_{2} + 4HF$.
$XeO_{3}$ is a colourless explosive solid with a pyramidal molecular structure.

Explore More

Similar Questions

Xenon reacts best with which of the following?

Which one of the following is a correct pair with respect to the molecular formula of a xenon compound and the hybridization state of xenon in it?

Consider the following transformations:
$I. XeF_6 + NaF \to Na^+[XeF_7]^-$
$II. 2PCl_{5(s)} \to [PCl_4]^+[PCl_6]^-$
$III. [Al(H_2O)_6]^{3+} + H_2O \to [Al(H_2O)_5OH]^{2+} + H_3O^+$
Which of the above transformations are correct?

Which of the following represents the correct pair of the molecular formula of a xenon compound and the hybridization of xenon?

Which of the following elements is $NOT$ radioactive?

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo